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structure of 14264-16-5

Bis(Triphenylphosphine)Nickel(II) Dichloride(CAS 14264-16-5)

CAS No.: 14264-16-5 Brand: MolBest
M. Ft.: C36H30Cl2NiP2 Cat. No: G4552750
M. Wt.: 654.17 MDL: MFCD00009592
Storage: Store in a cool,dry area. Use: For laboratory research use only
HS CODE: 29310095 UN No.: UN 3260
Purity Grade Package Stock Price Quantity
98%
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RG 5G In Stock 4 USD
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RG 25G In Stock 6 USD
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RG 100G In Stock 18 USD
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RG 500G In Stock 51 USD
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RG 2.5KG In Stock 349 USD
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RG 10KG In Stock 1378 USD
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Applications of 14264-16-5

Bis(triphenylphosphine)nickel(II)chloride finds applications primarily in organic synthesis as a catalyst. It is utilized in:

  • Suzuki Reactions: Although less active than some alternatives, it can still facilitate cross-coupling reactions.
  • Alkyne Trimerizations: First described by Walter Reppe, this compound is effective in promoting these reactions.
  • Carbonylation Reactions: It plays a role in synthesizing carbonyl compounds from alkenes and carbon monoxide.

Physical and chemical properties of 14264-16-5

Boiling Point

377 °C

Density

1.1 g/cm³

Exact Mass

652.05500

Exposure Limits

NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3

Flash Point

182 °C c.c.

H Bond Acceptors

0

H Bond Donors

0

Index of Refraction

MAX ABSORPTION (DILUTED ALCOHOL): 260 NM (LOG E= 4.0); INDEX OF REFRACTION: 1.6358 @ 80 °C/D

LogP

5.69

Melting Point

80 °C

Molecular Formula

C36H30Cl2NiP2

Molecular Weight

654.17000

Odor

ODORLESS

PSA

27.18000

Sensitivity

Hygroscopic

Solubility

Solubility in water, mg/l at 25 °C: 0.09 (very poor)

Storage condition

Inert atmosphere,Room Temperature

Vapour Pressure

Vapor pressure, Pa at 50 °C: 0.017

Water Solubility

insoluble

Spectrums of 14264-16-5

Attention:
1.The NMR spectrum displayed on the page is a pre-sale reference spectrum and may differ from that of the actual received batch.
2.The accompanying documentation will include the NMR spectrum and purity analysis data for the shipped batch.
Physical sample testing spectrum (NMR) of 14264-16-5

Retrosynthesis analysis of 14264-16-5


Q&A for CAS 14264-16-5

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Download SDS of 14264-16-5

Pictograms

Signal Word

Danger

Hazard Statements

H302 Harmful if swallowed
H317 May cause an allergic skin reaction
H350 May cause cancer
H412 Harmful to aquatic life with long lasting effects

Safety Data Sheet

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